The Sol-to-Gel Transition by Plinio Innocenzi

Author:Plinio Innocenzi
Language: eng
Format: epub, pdf
ISBN: 9783030200305
Publisher: Springer International Publishing

This is very important to catch because the sol to gel transition is not a thermodynamic event but a continuous transition, so there is not a specific value of temperature, pressure, and volume which describes the transition event which is continuous and defined in statistical terms. It is a series of non-equilibrium aggregation processes that lead to a sol to gel transition.

If we take the p-value as a reference for a transition from a sol to gel, we see that if p is lower than pc, we still have a sol, while a value of p higher than pc indicates the formation of a gel:

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